WebApr 16, 2024 · A fundamental theory is presented for the mechanical response of polymer networks undergoing large deformation which seamlessly integrates statistical mechanical principles with macroscopic thermodynamic constitutive theory. Our formulation permits the consideration of arbitrary polymer chain behaviors when interactions among chains may … WebJun 1, 2024 · The importance of polymer network topology was established early by Flory 35, 36, who derived several important theories (e.g., affine network theory [35] and the Flory–Rehner equation [37]) under the assumption of an idealized, defect-free network topology.However, the correlation of network topology with bulk properties has been …

A new transient network model for associative polymer networks

WebSep 16, 2016 · Elasticity, one of the most important properties of a soft material, is difficult to quantify in polymer networks because of the presence of topological molecular defects in these materials. Furthermore, ... The results led to a real elastic network theory (RENT) that describes how loop defects affect bulk elasticity. WebAug 5, 2014 · A statistical theory was proposed for the degradation (random scission of chains) of a network having f-functional nodes in the case where all chains contain … craigslist agawam ma apartment for rent

Toughening hydrogels through force-triggered chemical ... - Science

WebApr 14, 2024 · Both for the random and nonrandom statistical networks whose cycle rank is r, a linear relationship Rg 2 = a r D applies. The ratio ϕ of a r against the corresponding ring-free architecture a 0 , ϕ r = a r / a 0 has a universal relationship applicable both for the random and nonrandom networks with ϕ r ∝ r −0.25 for large r ’s, and an empirical … WebKeywords. Polymer Network. Network Chain. Rubber Elasticity. Strain Energy Density Function. Network Junction. These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves. Download chapter PDF. WebDec 10, 2024 · Dynamics of a polymer gel network is described by the theory proposed by Tanaka, Hocker, and Benedek (THB) that gives the diffusion coefficient of a polymer … diy concrete worktops uk